2012 Publications

1. Nature Chem. 2012, 4, 405-409.

A Au-Catalyzed Enantioselective Cope Rearrangement of Achiral 1,5- Dienes

Felix, R. J.; Weber, D.; Gutierrez, O.; Tantillo, D. J.; Gagné, M. R.

2. J. Org. Chem. 2012, 77, 8845-8850.

Analogies Between Synthetic and Biosynthetic Reactions in which [1,2]-Alkyl Shifts are Combined with Other Events-Dyotropic, Schmidt and Carbocation Rearrangements

Gutierrez, O.; Tantillo, D. J.

3. Chem. Eur. J. 2012, 18, 11029-11035.

Reexamining the Mechanisms of Competing [3,3] and [3,5] Sigmatropic

Shifts of 1,3,7 Octatriene

Gutierrez, O.; Harrison, J. G.; Pemberton, R. P.; Tantillo, D. J.

4. J. Am. Chem. Soc. 2012, 134, 6528-6531.

Stereocontrol in a Combined Allylic Azide Rearrangement and Intramolecular Schmidt Reaction: Application to Asymmetric Synthesis of Pinnaic Acid

Liu, R.; Gutierrez, O.; Tantillo, D. J.; Aubé, J.

5. J. Mass Spectrom. 2012, 47, 676-686.

Fragmentation of Oxime and Silyl-oxime Ether Odd-electron Positive Ions by the McLafferty Rearrangement: New Insights on Structural Factors that Promote α, β-Fragmentation

Laulhe, S.; Bogdanov, B.; Johannes, L. M.; Gutierrez, O.; Harrison, J. G.; Tantillo, D. J.; Zhang, X.; Nantz, M. H.

6. J. Org. Chem. 2012, 77, 640-647. Mechanism of the Acid Promoted Intramolecular Schmidt Reaction. Theoretical Assessment of the Importance of Lone Pair-Cation, Cation-pi and

Steric Effects in Controlling Regioselectivity

Gutierrez, O.; Aubé, J.; Tantillo, D. J.